Solvent extraction of dihalogenocuprate (I) with triphenylmethane dyes and spectrophotometric determination of copper.
نویسندگان
چکیده
منابع مشابه
Extractive spectrophotometric methods for determination of terbinafine hydrochloride in pharmaceutical formulations using some acidic triphenylmethane dyes
Three simple and sensitive extractive spectrophotometric methods have been described for the assay of terbinafine hydrochloride either in pure form or in pharmaceutical formulations. The developed methods involve formation of coloured chloroform extractable ion-pair complexes of the drug with bromothymol blue (BTB), bromophenol blue (BPB) and bromocresol green (BCG) in acidic medium. The extrac...
متن کاملSolvent Extraction and Spectrophotometric Determination of Magnesium by Paratoly l-2-Thenohydroxamic Acid and Quinalizarin
Magnesium is extracted with a chloroform solution of N-p-tolyl-2- thenohydroxamic acid (PTTHA) from aqueous solution of pH 9.5 .Mg-PTTHA complex is colourless and the colour is developed by adding quinalizarin into the extract. lmax and e of the complex are 590nm and 2.8´103 Lmol -1cm-1respectively.Most common ions do not interfere in the determination of magnesi...
متن کاملSolvent extraction, spectrophotometric determination of copper (II) from environmental samples using o-methylphenyl thiourea as a novel reagent
A simple and rapid method has been developed for solvent extraction and spectrophotometric determination of copper (II) using o-methylphenyl thiourea (OMPT) as a sensitive reagent. The basis of proposed method is formation of copper (II)-OMPT complex. Copper (II) was extracted with 0.020 mol L-1 OMPT in chloroform from aqueous solution in 0.075 mol L-1 potassium iodate. The absorbance of comple...
متن کاملExtraction of Traces of Copper as Tetra-Butylammonium Tetrathiocyanato Copper (II) and Its Spectrophotometric Determination Using Eriochrome Black T
An extraction-spectrophotometric method for the determination of traces of copper (II) is described. The method is based on the quantitative extraction of copper as tetrabutylammonium tetrathiocyanato copper (II) into methyl isobutyl ketone, followed by spectrophotometric determination, using eriochrome black T as a metallochromic indicator. The red-violet mixed complex of copper absorbs at...
متن کاملSpectrophotometric Determination of Copper
The utility of Patton and Reeder’s indicator, HHSNNA, for the trace spectrophotometric and visual colorimetric determination of Cu 2+ is explored. A wine red complex of composition 1:1 is found to be formed between Cu 2+ and HHSNNA. The complex has λmax at 530 nm with ε = 25,558 L mole -1 cm -1 and is stable for more than 2 hrs. Beer’s law is obeyed between 0 to 1.5 ppm. The developed procedure...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Analytical Sciences
سال: 1989
ISSN: 0910-6340,1348-2246
DOI: 10.2116/analsci.5.745